Batteries, Fuel Cells and Corrosion: Quiz

7 questions

  1. Question 1EasyWhat happens when a rechargeable battery is charged?
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    Answer: An external current drives the cell reaction in reverse

    Charging is electrolysis: electrical energy forces the non-spontaneous reverse reaction, restoring the reactants.

  2. Question 2EasyWhat is the only product of a hydrogen–oxygen fuel cell?
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    Answer: Water

    Overall reaction: 2H₂ + O₂ → 2H₂O.

  3. Question 3EasyIn which conditions does an iron nail rust fastest?
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    Answer: Salt water open to air

    Rusting needs oxygen and water; dissolved salt makes the water a better electrolyte and speeds the reaction.

  4. Question 4MediumWhich metal could be used as a sacrificial anode to protect a steel pipeline?
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    Answer: Magnesium

    Magnesium (E° −2.37 V) is oxidized more easily than iron (−0.44 V), so it corrodes instead. Copper, silver and tin are less reactive than iron.

  5. Question 5MediumWhat is E°(cell) for rusting, 2Fe + O₂ + 4H⁺ → 2Fe²⁺ + 2H₂O? (O₂/H₂O +1.23 V; Fe²⁺/Fe −0.44 V)
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    Answer: 1.67 V

    E°cell = E°cathode − E°anode = 1.23 V − (−0.44 V) = 1.67 V. 0.79 V comes from adding the values.

  6. Question 6HardWhat is ΔG° per mole of H₂ in a hydrogen fuel cell? (n = 4 for 2H₂ + O₂; E° = 1.23 V)
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    Answer: −237 kJ

    ΔG° = −4 × 96 485 C/mol × 1.23 V = −475 kJ for 2 mol H₂, which is −237 kJ per mole of H₂.

  7. Question 7HardWhy does a scratched tin coating make iron rust faster?
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    Answer: Iron becomes the anode, because iron is more reactive than tin

    Where both metals touch the electrolyte, the more reactive iron is oxidized and the tin acts as the cathode, speeding corrosion of the iron.