Acid–Base Properties of Salts: Quiz

7 questions

  1. Question 1EasyWhich salt gives a basic solution?
    Show answer

    Answer: K₂CO₃

    CO₃²⁻ is the conjugate base of a weak acid, so it takes protons from water and forms OH⁻. K⁺ is neutral.

  2. Question 2EasyWhich salt gives an acidic solution?
    Show answer

    Answer: NH₄Cl

    NH₄⁺ is the conjugate acid of the weak base NH₃ and donates a proton to water. Cl⁻ is neutral.

  3. Question 3EasyWhy is a solution of NaCl neutral?
    Show answer

    Answer: Neither Na⁺ nor Cl⁻ reacts with water to change [H⁺] or [OH⁻]

    Both ions come from a strong base and a strong acid, so they are far too weak to react with water.

  4. Question 4MediumKa of HCN is 4.9 × 10⁻¹⁰. What is Kb of CN⁻?
    Show answer

    Answer: 2.0 × 10⁻⁵

    Kb = Kw ÷ Ka = 1.0 × 10⁻¹⁴ ÷ 4.9 × 10⁻¹⁰ = 2.0 × 10⁻⁵. A very weak acid has a fairly strong conjugate base.

  5. Question 5HardWhat is the pH of 0.10 mol/L NaCN? (Kb of CN⁻ = 2.0 × 10⁻⁵)
    Show answer

    Answer: 11.15

    [OH⁻] ≈ √(2.0 × 10⁻⁵ × 0.10) = 1.41 × 10⁻³ mol/L, pOH = 2.85, pH = 14.00 − 2.85 = 11.15. 2.85 is the pOH.

  6. Question 6MediumThe equivalence point of a titration of ethanoic acid with NaOH has a pH of about:
    Show answer

    Answer: 9

    At equivalence the solution contains sodium ethanoate, a basic salt, so the pH is above 7 (about 8.7 for 0.050 mol/L).

  7. Question 7HardPut these 0.10 mol/L solutions in order of increasing pH: NaCN, NH₄Cl, NaCl, CH₃COONa.
    Show answer

    Answer: NH₄Cl, NaCl, CH₃COONa, NaCN

    NH₄Cl is acidic; NaCl is neutral; CH₃COO⁻ (Kb 5.6 × 10⁻¹⁰) is a weaker base than CN⁻ (Kb 2.0 × 10⁻⁵), so NaCN has the highest pH.