Titration Curves: Flashcards

9 cards

  1. Question
    What is a titration curve?
    Answer

    A graph of the pH of the mixture against the volume of titrant added.

  2. Question
    What is the equivalence point?
    Answer

    The point where just enough titrant has been added to react completely with the analyte, according to the balanced equation.

  3. Question
    What is the pH at the equivalence point of a strong acid–strong base titration?
    Answer

    7.00 (at 25 °C), because the salt formed is neutral.

  4. Question
    Is the equivalence point of a weak acid–strong base titration above or below 7?
    Answer

    Above 7, because the conjugate base of the weak acid is weakly basic.

  5. Question
    What is the pH at the half-equivalence point of a weak acid titration?
    Answer

    pH = pKa, because [HA] = [A⁻] there.

  6. Question
    What is the end point?
    Answer

    The point where the indicator changes colour. Ideally it matches the equivalence point.

  7. Question
    Which indicator suits a weak acid–strong base titration?
    Answer

    Phenolphthalein (changes around pH 8.2–10.0), within the steep jump.

  8. Question
    Is the equivalence point of a strong acid–weak base titration above or below 7?
    Answer

    Below 7, because the conjugate acid of the weak base is weakly acidic.

  9. Question
    Why are titrations so precise near the equivalence point?
    Answer

    The pH changes very steeply there, so a single drop causes a large, easily seen change.