Titration Curves: Quiz

7 questions

  1. Question 1EasyWhat is the pH at the equivalence point when HCl is titrated with NaOH?
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    Answer: 7.00

    Strong acid + strong base gives a neutral salt (NaCl), so the equivalence point is at pH 7.00 (25 °C).

  2. Question 2MediumAcetic acid is titrated with NaOH. At the equivalence point, the pH is…
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    Answer: above 7

    At equivalence the solution contains acetate, a weak base, so the pH is above 7 (8.72 for 0.100 M solutions).

  3. Question 3MediumAt the half-equivalence point of a weak acid titration, the pH equals…
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    Answer: the pKa of the acid

    Half the acid has been converted to its conjugate base, so [HA] = [A⁻] and pH = pKa + log(1) = pKa.

  4. Question 4EasyWhat volume of 0.100 M NaOH reaches equivalence with 25.00 mL of 0.100 M HCl?
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    Answer: 25.0 mL

    Moles HCl = 0.100 × 0.02500 = 0.00250 mol; volume NaOH = 0.00250 ÷ 0.100 = 0.0250 L = 25.0 mL.

  5. Question 5Hard25.00 mL of 0.100 M HCl is titrated with 0.100 M NaOH. What is the pH after 12.50 mL of NaOH has been added?
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    Answer: 1.48

    HCl left = 0.00250 − 0.00125 = 0.00125 mol in 37.50 mL: [H₃O⁺] = 0.0333 M, pH = 1.48. The answer 1.30 forgets that the volume has increased.

  6. Question 6MediumWhich indicator is best for titrating acetic acid with NaOH?
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    Answer: Phenolphthalein (pH 8.2–10.0)

    The equivalence point is at about pH 8.7, inside the steep jump where phenolphthalein changes colour. Methyl orange would change far too early.

  7. Question 7EasyWhy does a 0.100 M acetic acid titration start at a higher pH than a 0.100 M HCl titration?
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    Answer: Acetic acid ionizes only partly

    A weak acid releases fewer H₃O⁺ ions than a strong acid of the same concentration (pH 2.88 vs 1.00).